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Question

In the titration of NaOH and HCl, which of the following indicator will be used?

A
Methyl orange
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B
Methyl red
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C
Both A and B
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D
None of the above
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Solution

The correct option is D None of the above
HCl is a strong acid and NaOH is a strong base. Therefore, titrating one against the other yields a complete reaction. The titration is complete when the pH reaches 7.0. Methyl orange would not be appropriate here, as the color change occurs at between 3.1 and 4.4 in an aqueous solution. Not helpful in this case. A much better choice here would be phenolphthalein, which goes from clear to pink at a pH of 8.2 still not exactly 7.0, but well within the rapid transition point curve.

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