The correct option is A the breakdown field of air is reached
On one hand, we have the equation V=14πε0qr i.e, V∝1r, whereas on the other hand, the natural tendency for positive charge is to move higher to lower potential. Thus, provided we are somehow able to introduce the small charged sphere into layer one. We can in this way pile larger and larger amount of charge on the latter. The potential of the outer sphere would always keep rising, at least unitl it reaches the breakdown field of air.