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Question

In van der Waals equation at constant temperature 300 K, if a=1.4 atm L2 mol2, V=100 mL, n=1 mol, then what is the pressure of the gas?

A
42 atm
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B
210 atm
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C
500 atm
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D
106 atm
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Solution

The correct option is D 106 atm
At moderate pressure van der Waals equation is given as :
(P+an2V2)(V)=nRT
(P+1.4(0.1)2)(0.1)=1×0.082×300
Solving,
P=106 atm

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