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Question

In which case geometry of the molecule is pyramidal?

A
N(CH3)3
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B
N(SiH3)3
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C
Both (a) and (b)
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D
None of these
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Solution

The correct option is A N(CH3)3

N(CH3)3 is pyramidal.
N(SiH3)3 is planar: The N atom in N(SiH3)3 is sp2 hybridized. it has a lone pair of electron which is forming a bond with d-orbital of Si atom forming dπ and pπ bonding.

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