The correct option is B Br2
Boiling point and melting point is determined by the strength of van der Waals forces in the case of non-polar molecules which inturn depends on the size of the molecule.
Since Br2 is non-polar, the van der Waals forces will determine its melting and boiling point. Since the other given molecules are polar, dipole-dipole interactions will determine their melting and boiling point.