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Question

In which of following molecules, π - electron density in ring is minimum?

A
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B
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C
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D
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Solution

The correct option is D
NO2 group produces M effect, i.e., electron density decreases in the ring. OCH3 and NH2 groups produces +M effect, i.e., electron density increases in the ring.
In option D, two NO2 groups are present. At meta position it will produce I effect which will also lead to decrease in electron density of the ring.

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