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Question

In which of the above compounds, the indicated bond is of greater strength?
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A
I
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B
II
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C
Both are equal
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D
Cannot determine
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Solution

The correct option is A I
sp2 carbon atom is more electronegative than sp3 carbon atom. The electronegativity difference between sp2 carbon atom and bromine atom is less than the electronegativity difference between sp3 carbon atom and bromine atom.
Hence, the extent of sharing of electron pair in the bond between sp2 carbon atom and bromine atom is more than the extent of sharing of electron pair in the bond between sp3 carbon atom and bromine atom.
So, the bond between sp2 carbon atom and bromine atom is stronger than the bond between sp2 carbon atom and bromine atom.

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