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Question

In which of the following cells, use of salt bridge to eliminate liquid junction potential is not necessary?

A
PtH2(g)|HCl|AgCl(s)|Ag
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B
Hg|Hg2Cl2(s)|KClsaturated|HCl(aq)|H2(g)Pt
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C
Zn|ZnSO4||CuSO4|Cu
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D
Zn|ZnSO4|Fe3+(aq),Fe2+(aq)|Pt
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Solution

The correct option is A PtH2(g)|HCl|AgCl(s)|Ag
In the cell PtH2(g)|HCl|AgCl(s)|Ag, use of salt bridge to eliminate liquid junction potential is not necessary as it involves only one (Cl) ion.

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