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Question

In which of the following compound, cations occupy alternate tetrahedral voids in cubic closed packing (ccp)?

A
ZnS
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B
NaCl
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C
Na2O
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D
CaF2
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Solution

The correct option is A ZnS
Zns has ccp type structure, in which S2 ions occupy corner and face centre positions, while Zn2+ ions are placed at alternate tetrahedral voids.

Hence, option A is correct.

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