In which of the following compounds does manganese have the maximum radius?
We already know that if the positive charge is higher, effective nuclear charge on the electrons remaining increases and size decreases.
Therefore, higher charge ⇒ smaller size
MnO2 → Mn+4
MnO → Mn+2
KMnO4 → Mn+6
K3[Mn(CN)6] → Mn+3
So, the answer should be KMnO4