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Question
In which of the following compounds, the C−Cl bond ionisation shall give most stable carbonium ion?
In which of the following compounds, the C−Cl bond ionisation shall give most stable carbonium ion?
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Solution
The correct option is D
Option (a) will give benzyl carbocation. Option (b) will give primary carbocation destabilized by −NO2 group (c) will give secondary carbocation and (d) will give tertiary carbocation.
Here (d) is slightly more stable than (a).
Option (a) will give benzyl carbocation. Option (b) will give primary carbocation destabilized by −NO2 group (c) will give secondary carbocation and (d) will give tertiary carbocation.
Here (d) is slightly more stable than (a).
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