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Question

In which of the following crystals of ionic compounds would you expect maximum distance between the centres of cations and anions?

A
LiF
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B
CsF
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C
CsI
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D
LiI
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Solution

The correct option is C CsI

Ionic radii is the distance between the nucleus of an ion and a point up to which the nucleus has its influence on its electron cloud.


The size of ions increases on moving from top to bottom in a group.


Hence, the maximum distance between the centres of cations and anions is in CsI because Cs is the largest cation and I is the largest anion.

Hence, the correct option is C.


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