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Question

In which of the following electrochemical cell overall cell reaction is :
HgO(s)+H2(g)Hg(l)+H2O(l)

A
Pt|H2(g)|H+(aq)|HgO(s)|Hg(l)|Pt
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B
Pt|H2(g)|NaOH(aq)|HgO(s)|Hg(l)|Pt
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C
Pt|H2(g)|H+||NaOH(aq)|HgO(s)|Hg(l)|Pt
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D
Pt|H2(g)|H+||HgO(s)|Hg(l)|Pt
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Solution

The correct option is B Pt|H2(g)|NaOH(aq)|HgO(s)|Hg(l)|Pt
Pt|H2(g)|NaOH(aq)|HgO(s)|Hg(l)|Pt

LHE reaction : H2(g)+2OH2H2O(l)+2e

RHE reaction : HgO(s)+H2O(l)+2eHg(l)+2OH


Net cell reaction : HgO(s)+H2(g)Hg(l)+H2O

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