In which of the following electrochemical cell overall cell reaction is : HgO(s)+H2(g)→Hg(ℓ)+H2O(ℓ)
A
Pt|H2(g)|H+(aq)|HgO(s)|Hg(ℓ)|Pt
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B
Pt|H2(g)|NaOH(aq)|HgO(s)|Hg(ℓ)|Pt
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C
Pt|H2(g)|H+||NaOH(aq)|HgO(s)|Hg(ℓ)|Pt
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D
Pt|H2(g)|H+||HgO(s)|Hg(ℓ)|Pt
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Solution
The correct option is BPt|H2(g)|NaOH(aq)|HgO(s)|Hg(ℓ)|Pt Pt|H2(g)|NaOH(aq)|HgO(s)|Hg(ℓ)|Pt LHE reaction : H2(g)+2OH−→2H2O(ℓ)+2e RHE reaction : HgO(s)+H2O(ℓ)+2e→Hg(ℓ)+2OH− Net cell reaction : HgO(s)+H2(g)→Hg(ℓ)+H2O