The correct options are
A Cu2S,PbS
B PbS,HgS
In the self reduction process, metal sulfide reacts with metal oxide to form free metal.
The conversion of metal ore to crude metal by self reduction process is carried for the pairs Cu2S,PbS and PbS,HgS.
For example cupric oxide reacts with cupric sulphide to form crude copper metal.
2PbS+3O2→2PbO+2SO2
PbS+2PbO→3Pb+SO2 (self reduction)
Cu2S+2Cu2O→6Cu+SO2
HgS+2HgO→3Hg+SO2