In which of the following pairs, the two species are iso-structural?

$B r O_{3}^{-}$ and $X e O_{3}$

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$S F_{4}$ and $X e F_{4}$

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$S r O_{3}^{2 -}$ and $N O_{3}^{-}$

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$B F_{3}$ and $N F_{3}$

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Solution

The correct option is A
$B r O_{3}^{-}$ and $X e O_{3}$

First, let's take a look at the structure of $X e O_{3}$ :

Now, let's look at the bromate anion:

Both $B r O_{3}^{-}$ and $X e O_{3}$ have their respective central atoms in $s p^{3}$ and both are pyramidal. Hence iso-structural!

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