In which of the following reactions does the heat change represent the heat of formation of water?
A
2H2(g)+O2(g)→2H2O(l);ΔH=116Kcal
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B
H2(g)+12O2(g)→H2O(l);ΔH=−6.8Kcal
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C
H+(aq)+OH−(aq)→H2O(l);ΔH=13.7Kcal
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D
C2H2(g)+2O2(g)→2CO2(g)+H2O(l);ΔH=310Kcal
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Solution
The correct option is BH2(g)+12O2(g)→H2O(l);ΔH=−6.8Kcal For the heat of formation one mole of product is formed from its constituent elements in their standard state formation of H2O(l) H2(g)+12O2(g)→H2O(l)