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Question

In which of the following reactions, hydrogen is acting as an oxidising agent?

A
With iodine to give hydrogen iodide
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B
With lithium to give lithium hydride
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C
With nitrogen to give ammonia
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D
With sulphur to give hydrogen sulphide
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Solution

The correct option is B With lithium to give lithium hydride
An oxidising agent itself undergoes reduction. Its oxidation number decreases. When H2 is converted to hydride ion H, it itself is reduced and acts as oxidisng agent.
In the following reactions, hydrogen is acting as an oxidising agent.
With lithium to give lithium hydride
H2+2Li2LiH

In the following reactions, hydrogen is acting as a reducing agent.
With iodine to give hydrogen iodine
H2+I22HI
With nitrogen to give ammonia
3H2+N22NH3
With sulphur to give hydrogen sulphide
H2+SH2S

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