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Question

In which of the following solvents, KI has highest solubility? The dielectric constant (ϵ) of each liquid is given in parentheses.

A
C6H6(ϵ=0)
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B
(CH3)2CO(ϵ=21)
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C
CH3OH(ϵ=32)
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D
CCl4(ϵ=0)
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Solution

The correct option is C CH3OH(ϵ=32)
KI is an ionic compound. Hence, it will be most soluble in apolar solvent, which has a high value of dielectric constant. Hence, CH3OH with the highest value of dielectric constant among the given options will provide high solubility.

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