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Question

In which of the following species the interatomic bond angle is 109o28′ ?

A
NH3,(BF4)1
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B
(NH4)+,BF3
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C
NH3,BF3
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D
(NH2)1,BF3
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Solution

The correct option is A NH3,(BF4)1
Both NH3 and (BF4)1 have same hybridisation, sp3, we know in NH3, there is a lone pair, which makes the bond angle 109°28.
(BF4)1 and NH3 has pyramidal structure. So they have same bond angle.

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