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Question

In which of the following, the hydration energy is higher than the lattice energy?

A
BaSO4
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B
MgSO4
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C
CaSO4
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D
SrSO4
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Solution

The correct option is B MgSO4
Ionic nature of alkaline metal sulphate increases from Be to Ba.
BeSO4<MgSO4<CaSO4<SrSO4<BaSO4
Solubility decreases from BeSO4 to BaSO4 as Be2+ and Mg2+ are of small size, so their hydration energy is high.
Hydration energy > Lattice energy

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