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Byju's Answer
Standard XII
Physics
Calorimetry
In which of t...
Question
In which of the following
△
E
=
△
H
?
A
N
2
O
4
(
g
)
⟶
2
N
O
2
(
g
)
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B
2
S
O
2
(
g
)
+
O
2
(
g
)
⟶
2
S
O
3
(
g
)
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C
H
2
(
g
)
+
I
2
(
g
)
⟶
2
H
I
(
g
)
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D
H
2
(
g
)
+
1
2
O
2
(
g
)
⟶
H
2
O
(
l
)
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Solution
The correct option is
C
H
2
(
g
)
+
I
2
(
g
)
⟶
2
H
I
(
g
)
Solution:- (C)
H
2
(
g
)
+
I
2
(
g
)
⟶
2
H
I
(
g
)
Δ
H
=
Δ
E
+
Δ
n
g
R
T
Hence
Δ
H
=
Δ
E
for
Δ
n
g
=
0
Hence for the reaction,
H
2
(
g
)
+
I
2
(
g
)
⟶
2
H
I
(
g
)
Δ
n
g
=
n
P
−
n
R
=
2
−
(
1
+
1
)
=
0
∴
Δ
H
=
Δ
E
Suggest Corrections
0
Similar questions
Q.
Determine
K
p
for the following reactions:
(a)
C
O
(
g
)
+
H
2
O
(
g
)
⇌
C
O
2
(
g
)
+
H
2
(
g
)
;
K
c
=
23.2
at
600
K
(b)
N
2
O
4
(
g
)
⇌
2
N
O
2
(
g
)
;
K
c
=
4.62
×
10
−
3
M
at
298
K
(c)
2
S
O
2
(
g
)
+
O
2
(
g
)
⇌
2
S
O
3
(
g
)
;
K
c
=
2.8
×
10
2
M
−
1
at
1000
K
Q.
For which of the following equation will
Δ
H
be equal to
Δ
U
.
Q.
For which of the following
Δ
H
is not equal to
Δ
U
Q.
The following reaction occurs at 500 K. Arrange them in the order of increasing tendency to proceed to completion.
(I)
H
2
(
g
)
+
I
2
(
g
)
⇌
2
H
I
(
g
)
;
K
c
=
1.8
×
10
−
3
(II)
N
2
O
4
⇌
2
N
O
2
(
g
)
;
K
c
=
3
×
10
−
3
(III)
P
C
l
5
(
g
)
⇌
P
C
l
3
(
g
)
+
C
l
2
(
g
)
;
K
c
=
1.3
×
10
−
4
(IV)
2
S
O
3
(
g
)
⇌
2
S
O
2
(
g
)
+
O
2
(
g
)
;
K
c
=
1.3
×
10
−
5
Q.
Reaction
K
1
2
N
2
(
g
)
+
O
2
(
g
)
⇋
N
O
2
K
1
2
N
O
2
(
g
)
⇌
N
2
O
4
(
g
)
K
2
Using the above equations, write down expression for
K
of the following reaction:
N
2
O
4
(
g
)
⇌
N
2
(
g
)
+
1
2
O
2
(
g
)
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