In which one of the following equilibria, the increase of pressure over the equilibrium will favour the backward reaction?
A
Decomposition equilibrium of HI
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B
Formation equilibrium of SO3
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C
Decomposition equilibrium of NH3
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D
Formation equilibrium of PCl5
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Solution
The correct option is C Decomposition equilibrium of NH3 In the decomposition reaction of NH3 the number of moles of products formed is greater than that of reactant involved. 2NH3⇌N2+3H2 According
to Le-Chatelier's principle, the increase of pressure on a chemical
equilibrium shift in that direction in which the number of gaseous
molecules decreases and vice-versa thus in this reaction, increase in
pressure favours the backward reaction.