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Question

In which one of the following equilibria, the increase of pressure over the equilibrium will favour the backward reaction?

A
Decomposition equilibrium of HI
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B
Formation equilibrium of SO3
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C
Decomposition equilibrium of NH3
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D
Formation equilibrium of PCl5
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Solution

The correct option is C Decomposition equilibrium of NH3
In the decomposition reaction of NH3 the number of moles of products formed is greater than that of reactant involved.
2NH3N2+3H2
According to Le-Chatelier's principle, the increase of pressure on a chemical equilibrium shift in that direction in which the number of gaseous molecules decreases and vice-versa thus in this reaction, increase in pressure favours the backward reaction.

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