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Standard IX

Chemistry

Anomalous Solubility

In which solu...

Question

In which solution, AgCl has minimum solubility? 1. 0.01M NaCl 2. 0.01M CaCl2 3. 0.05M AgNO3 4. pure water

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Solution

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Similar questions

Q. Let the solubilities of AgCl in pure water, 0.01 M

{C a C l}_{2}

, 0.01 M NaCl % 0.05 M

{A g N O}_{3}

s_{1}, s_{2}, s_{3}

s_{4}

respectively. What is the correct order of these quantities ? Neglect any complexation.

The solubilities of $A g C l$ in water, 0.01 M $C a C l_{2}$ , 0.01 M $N a C l$ and 0.05 M $A g N O_{3}$ are denoted by $S_{1}, S_{2}, S_{3}, S_{4}$ respectively. Which of the following relationships are correct? $K_{s p} = 1.8 \times 10^{- 10}$

Q. Solubility of AgCl in water 0.01M

C a C l_{2}

, 0.01M NaCl and 0.05M

A g N O_{3}

are

S_{1}, S_{2}, S_{3}

and

S_{4}

respectively then

(K_{s p} A g C l = 10^{- 10} M^{2})

Q. Predict if there will be any precipitate by mixing

50

mL of

0.01

N a C l

and

50

mL of

0.01

A g N O_{3}

solution. The solubility product of

A g C l

1.5 \times 10^{- 10}

Q. What is the concentration of

A g^{+}

ion in

0.01 M A g N O_{3}

that is also

1.0 M N H_{3}

?
Will

A g C l

precipitate from a solution that is

0.01 M A g N O_{3}

0.01 M N a C l

and

1 M N H_{3}

?
Given : Formation constant,

K_{f} o f [A g (N H_{3})_{2}]^{+} = 1.70 \times 10^{7} a n d K_{s p} A g C l = 1.8 \times 10^{- 10}

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