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Question

In zinc blende structure:

A
zinc ions occupy half of the tetrahedral sites.
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B
each Zn2+ ion is surrounded by six sulphide ions
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C
each S2 ion is surrounding by six Zn2+ ions
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D
it has bcc structure
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Solution

The correct options are
A zinc ions occupy half of the tetrahedral sites.
D it has bcc structure
Structure of Zinc Blende

Zinc blende has a FCC structure. In this sulphide ions are present at corners and zinc ions occupy half of the tetrahedral voids.

Each Zn+2 ion is surrounded by 4 S2 ion and each S2 ion is surrounded by 4 Zn+2

Hence, Options "A" & "D" are correct answers.

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