Incorrect statement among the following is
[0.77 Mark]
A
o-Nitrophenol and p-nitrophenol can be separated by steam distillation
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B
o-Nitrophenol is steam volatile
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C
Intramolecular hydrogen bonding exist in p-nitrophenol
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D
Boiling point of o-nitrophenol is less than that of p-nitrophenol
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Solution
The correct option is C Intramolecular hydrogen bonding exist in p-nitrophenol
The boiling point of o-nitrophenol is less than that of p-nitrophenol because of intramolecular hydrogen bonding in o-nitrophenol, As a result o-nitrophenol is steam volatile and can be separated from p-nitrophenol using steam distillation.