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Question

Increasing order of acid strength among p-methoxy phenol, p - methyl phenol and p - nitro phenol is:

A
p - methyl phenol < p - methoxy phenol < p - nitro phenol
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B
p - methoxy phenol < p - methyl phenol < p - nitro phenol
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C
p - nitro phenol < p - methoxy phenol < p - methyl phenol
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D
p - nitro phenol < p - methyl phenol < p - methoxy phenol
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Solution

The correct option is A p - methyl phenol < p - methoxy phenol < p - nitro phenol
Increasing acid strength:


Acidic strength α R,H,I
Acidic strength α 1+R,+H,+I
where
R = Resonance effect
H = Hyperconjugation effect
I = Inductive effect
NO2 shows R1 I
OCH3 shows +R1 I
CH3 shows +H1 +I

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