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Question

Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche) of 2fluoro ethanol is:

A
Eclipse,Gauche,Anti
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B
Gauche,Eclipse,Anti
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C
Eclipse,Anti,Gauche
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D
Anti,Gauche,Eclipse
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Solution

The correct option is D Eclipse,Gauche,Anti

The anticonformation is most stable in which F and OH groups are far apart as possible and minimum repulsion between two groups occurs.
In fully eclipsed conformation F and OH groups are so close that the steric strain is maximum .
Hence this conformation is most unstable.
The order of stability of these conformations is anti > gauche > partially eclipsed > fully eclipsed.

Increasing order of stability is in option A.

Hence,A is the correct answer.

1156690_1119256_ans_bf2c039fefc64157b5033035d0d7d46e.jpg

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