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Question

Increasing rate of SN1 reaction for the following compounds is:

A
I < II < III < IV
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B
II < I < III < IV
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C
I < II < IV < III
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D
II < I < IV < III
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Solution

The correct option is B II < I < III < IV
More stable carbocation intermediates, higher will be the rate for SN1 reaction.
The electronic effects by the substituents on the carbocation formed are as follow:

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