Indicate the correct statement for equal volumes of N2(g) and CO2(g) at 25∘C and 1atm.
A
The average translational KE per molecule is the same for N2 and CO2
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B
The rms speed remains constant for both N2 and CO2
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C
The density of N2 is less than that of CO2
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D
The total translational KE of both N2 and CO2 is the same
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Solution
The correct options are A The average translational KE per molecule is the same for N2 and CO2 C The density of N2 is less than that of CO2 D The total translational KE of both N2 and CO2 is the same As volume and pressure are equal so average translational KE per molecule is the same for N2 and CO2. But rms speed is different as it depends on molecular wt. urms=√3RTM. Also, total translational K.E. of both N2 and CO2 is the same.
Hence, Options "A", "C" & "D" are correct answers.