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Question

Indicate the σ and π bonds in the following molecules:

C6H6, C6H12, CH2Cl2, CH2 = C = CH2, CH3NO2, HCONHCH3

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Solution

(i) C6H6

There are six C–C sigma () bonds, six C–H sigma () bonds, and three C=C pi () resonating bonds in the given compound.

(ii) C6H12

There are six C–C sigma () bonds and twelve C–H sigma () bonds in the given compound.

(iii) CH2Cl2

There two C–H sigma () bonds and two C–Cl sigma () bonds in the given compound.

(iv) CH2 = C = CH2

There are two C–C sigma () bonds, four C–H sigma () bonds, and two C=C pi () bonds in the given compound.

(v) CH3NO2

There are three C–H sigma () bonds, one C–N sigma () bond, one N–O sigma () bond, and one N=O pi () bond in the given compound.

(vi) HCONHCH3

There are two C–N sigma () bonds, four C–H sigma () bonds, one N–H sigma bond, and one C=O pi () bond in the given compound.


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