Indicate whether the following conversions represent an oxidation, a reduction or none (neither oxidation nor reduction). (i) HClO3 to HClO4 (ii)NH+4 to NH3 (iii) NO2 to N2O4 (iv)HSO−3 to SO2−4 (v) H2O2 to H2O
A
(i) Oxidation (ii) Reduction (iii) None (iv) None (v) Oxidation
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B
(i) Oxidation (ii) None (iii) None (iv) Oxidation (v) Reduction
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C
(i) Reduction (ii) Oxidation (iii) Reduction (iv) None (v) Reduction
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D
(i) Oxidation (ii) Reduction (iii) None (iv) Reduction (v) Reduction
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Solution
The correct option is B (i) Oxidation (ii) None (iii) None (iv) Oxidation (v) Reduction
Oxidation is loss of electron and reduction is the gain of electron. Thereby assigning the oxidation number on central atom in each molecule for each conversion will determine oxidation or reduction process. Considering oxidation number of H=+1,O=−2 we get oxidation state as:
(i) Oxidation number of Cl in HClO3→HClO4
H+5ClO3→+7HClO4
Oxidation number of Cl changes from +5 to +7, by losing two electron is oxidation process.
(ii) Oxidation number of N in NH+4→NH3
−3NH+4→−3NH3 Oxidation number of N does not change. Thus its neither oxidation nor reduction.
(iii)Oxidation number of N in NO2→N2O4
+4NO2→+4N2O4 Oxidation number of N does not change. Thus its neither oxidation nor reduction.
(iv)Oxidation number of S in HSO−3→SO2−4 H+4SO−3→+6SO42− Oxidation number of Schanges from +4 to +6, by losing two electron is oxidation process. (v) Oxidation number of S in H2O2→H2O H2−1O2→H2−2O Oxidation number of Ochanges from -1 to -2, by gaining one electron is reduction process. Therefore: (i) Oxidation(ii) None(iii) None(iv) Oxidation(v) Reduction