Insoluble nitrosoamines R 2 N - N - O on heating with conc- H 2 SO 4 produces secondary amines- This reaction is called -A- Liebermann-s nitroso reactionB- Etard reactionC- Corey House reactionD- Hoffmann mustard oil reaction

The correct option is A Liebermann’s nitroso reactionR_2N N R_2N N = O (2 AMINE) (NITROSO AMINE) ...

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Mustard Oil Test

Insoluble nit...

Question

Insoluble nitrosoamines $(R_{2} N - N = O)$ on heating with conc. $H_{2} S O_{4}$ produces secondary amines. This reaction is called :

Liebermann’s nitroso reaction

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Etard reaction

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Corey House reaction

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Hoffmann mustard oil reaction

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Solution

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(R_{2} N - N = O)

H_{2} S O_{4}

Primary amine on heating with $C S_{2}$ followed by excess of mercuric chloride gives Isothiocyanate. The reaction is called

R C O O H \to R C H_{2} C O O H

C_{2} H_{5} N H_{2} + C S_{2} + H g C l_{2} Δ - \to C_{2} H_{5} N = C = S + H g S + 2 H C l

$B a C l_{2} + H_{2} S O_{4} \to B a S O_{4} ↓ + 2 H C l$ .
The reaction given above is an example of:

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