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Question

Interlayer distance in graphite is:

A
Very small, the layers being tightly packed
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B
Many times larger than the covalent radius of carbon
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C
More than twice the covalent radius of carbon
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D
The same as the covalent radius of carbon
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Solution

The correct option is C More than twice the covalent radius of carbon

Graphite is composed of flat two - dimensional sheets or layers of carbon atom. Each sheet or layer consists of flat hexagonal rings of C-atoms. In each layer, each C-atom is linked to three C-atoms by a C-C covalent bond. The C-C bond length in each hexagonal ring is 141.5 pm, as each C-atom is sp2 hybridised, i.e., only three of the valence electrons of each C-atom are involved in forming σ bond (using sp2 hybrid orbitals). The fourth electron forms a π bond. The π-electrons are delocalized over the whole sheet, and as they are mobile, graphite conducts heat and electricity.


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