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Introduction

Intermolecula...

Question

Intermolecular hydrogen bond is present in which of the following pair of molecules?

S i H_{4}

and

S i F_{4}

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C H_{3} - O | | C - C H_{3}

and

C H C l_{3}

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H - O | | C - O H

and

C H_{3} - O | | C - O H

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C H_{3} O C H_{3}

and

H_{2} O_{2}

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Solution

The correct option is C $H - O | | C - O H$ and $C H_{3} - O | | C - O H$
Intermolecular hydrogen bond is present in $H - O | | C - O H$ and $C H_{3} - O | | C - O H$ pair of molecules as both compounds have intermolecular H-bonding amongst themselves and with water.

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C H_{3} - O | | C - O H

C H_{3} - O H

C H_{3} - O - C H_{3}

C H_{3} - O | | C - C H_{2} - O | | C - O - C_{2} H_{3}

C H_{3} - O H | C = C H - O | | C - O - C_{2} H_{5}

I . H N = C = O \leftrightarrow H - O - C \equiv N

I I . ¯ N = C = O \leftrightarrow N \equiv C - O^{-}

I I I . C H_{3} - O | | C - ¯ C H_{2} \leftrightarrow C H_{3} -^{-} C = C H_{2}

I V . C H_{3} - O | | C - C H_{3} \leftrightarrow C H_{3} - O H | C = C H_{2}

C H_{3} - O | | C - C H_{3}

X_{2}, O H^{-} - ---- \to

C H_{3} - O | | C - C H_{3}

\to X_{3} C - O | | C - C X_{3}

C H_{3} - O | | C - C H_{3}

O H^{-} - -- \to

C H_{3} - O | | C - O^{-} - C H X_{3}

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