Intramolecular H-bonding is present in:

O - n i t r o p h e n o l

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H C l

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H B r

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H F

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Solution

The correct option is A $O - n i t r o p h e n o l$
Intramolecular hydrogen bonding takes place in ortho-nitrophenol because of the $N O_{2}$ and OH molecules close proximity to each other and this disrupts the possibility of molecular association.

Hence, the correct option is A.

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