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Types of Hydrogen Bonding

Intramolecula...

Question

Intramolecular hydrogen bond is present in:

A

water

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B

o-nitrophenol

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C

p-nitrophenol

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D

methylamine

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Solution

The correct option is B o-nitrophenol
Intramolecular $H -$ bonding is present in ortho-nitrophenol.

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Q. Ortho-nitrophenol is steam volatile whereas para-nitrophenol is not. This is due to

1.

Intramolecular hydrogen bonding present in ortho-nitrophenol

2.

Intermolecular hydrogen bonding present in para-nitrophenol

3.

Intramolecular hydrogen bonding present in para-nitrophenol

4.

Inter-molecular hydrogen bonding present in ortho-nitrophenol.

Q. Assertion :Boiling point of p-nitrophenol is greater than that of o-nitrophenol. Reason: There is intramolecular hydrogen bonding in p-nitrophenol and intermolecular hydrogen bonding in o-nitrophenol.

Q. Assertion (A) : Ortho and para nitrophenols can be separated by steam distillation.
Reason (R) : Ortho nitrophenol exhibits intramolecular hydrogen bonding while para nitrophenol exists as associated molecules.

Q. Given below are two statement:

Statement I: o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II: o-Nitrophenol has high melting point due to hydrogen bonding.

Q. Assertion :p-Nitrophenol is a stronger acid than o-nitrophenol. Reason: Intramolecular hydrogen bonding makes the o-isomer weaker than the p-isomer

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