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Question

Iodide of Millon's base is

A
HgI2
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B
K2HgI4
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C
NH2HgOHgI
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D
NH4I
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Solution

The correct option is C NH2HgOHgI
When NH+4 ions are treated with Nessler's reagent (alkaline solution of K2HgI4), a brown ppt. of NH2HgOHgI or Hg2NIH2O (iodide of Millon's base) is formed.
2K2HgI4+NH2+2KOHNH2HgOHgIiodide of Millon's base+7KI+2H2O.

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