Ionisation constant of each HA (weak acid) and BOH (weak base) are 3.0×10−7 each at 298 K. The percentage degree of hydrolysis of BA at the dilution of 100 L is:
A
25
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B
50
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C
75
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D
40
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Solution
The correct option is C 25 For a salt of weak acid and weak base, BA,
h1−h=√Kh=√KωKaKb.
Ka=Kb=3×10−7 and Kw=10−14 Substitute the values in the above expression,
h1−h=√Kh=√10−14(3×10−7)2=13
Hence, h=0.25.
The percentage degree of hydrolysis of BABA at the dilution of 100 L is 25%