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Question

Ionisation constant of each HA (weak acid) and BOH (weak base) are 3.0×107 each at 298 K. The percentage degree of hydrolysis of BA at the dilution of 100 L is:

A
25
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B
50
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C
75
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D
40
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Solution

The correct option is C 25
For a salt of weak acid and weak base, BA,

h1h=Kh=KωKaKb.

Ka=Kb=3×107 and Kw=1014
Substitute the values in the above expression,
h1h=Kh=1014(3×107)2=13
Hence, h=0.25.

The percentage degree of hydrolysis of BABA at the dilution of 100 L is 25%



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