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Question

Ionization potential and electron affinity of fluorine are 17.42 and 3.45 eV respectively. The electronegativity of fluorine on Mulliken scale and Pauling scale is x & y ,then (x+y)2.023 is:

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Solution

(1) Mulliken's scale
Electronegativity =Ionisation potential + electron affinity2
Electronegativity =17.42+3.452=10.435=x
(2) Pauling scale
Electronegativity =Ionisation potential + electron affinity5.6
Electronegativity =17.42+3.455.6=3.73=y
(x+y)2.023=(10.435+3.73)2.023=7

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