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Byju's Answer
Standard XII
Chemistry
Representation of Cell
Is 1.0M H+ ...
Question
Is 1.0M
H
+
solution under
H
2
S
O
4
at 1.0atm capable of oxidising silver metal in the prescence of 1.0M
A
g
+
ion?
Open in App
Solution
Since
E
0
A
g
+
|
A
g
>
E
H
+
|
H
2
So
H
+
can only reduce
A
g
+
to
A
g
, or
H
+
can not Oxidises
A
g
to
A
g
+
. It can only reduces to
A
g
from
A
g
+
.
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Similar questions
Q.
Given
E
⊕
A
g
⊕
|
A
g
=
0.80
V
E
⊕
H
⊕
|
H
2
(
P
t
)
=
0.00
V
.
Assertion:
1.0
M
H
⊕
solution under
H
2
S
O
4
at 1.0 bar
(
≈
1.0
a
t
m
)
is capable of oxidizing silver metal in the presence of 1.0 M
A
g
⊕
ion.
Reason:
E
⊕
c
e
l
l
is positive.
Q.
Is 1.0 M
H
+
solution under
H
2
S
O
4
at 1.0 atm capable of oxidizing silver metal in the presence of 1.0 M
A
g
+
ion?
E
0
A
g
+
|
A
g
=
0.80
V
,
E
0
H
+
|
H
2
(
P
t
)
=
0.0
V
.
Q.
At
298
K
, given that:
C
u
(
s
)
|
C
u
2
+
(
1.0
M
)
|
|
A
g
+
(
1.0
M
)
|
A
g
(
s
)
E
o
c
e
l
l
=
0.46
V
Z
n
(
s
)
|
Z
n
2
+
(
1.0
M
)
|
|
C
u
2
+
(
1.0
M
)
|
C
u
(
s
)
E
o
c
e
l
l
=
1.10
V
Then, the
E
c
e
l
l
for the following reaction at
298
K
will be:
Z
n
(
s
)
|
Z
n
2
+
(
0.1
M
)
|
|
A
g
+
(
1.
0
M
)
|
A
g
(
s
)
Q.
Given that (at
T
=
298
K
)
C
u
(
s
)
|
C
u
2
+
(
1.0
M
)
|
|
A
g
+
(
1.0
M
)
|
A
g
(
s
)
E
∘
c
e
l
l
=
0.46
V
Z
n
(
s
)
|
Z
n
2
+
(
1.0
M
)
|
|
C
u
2
+
(
1.0
M
)
|
C
u
(
s
)
E
∘
c
e
l
l
=
1.10
V
The
E
c
e
l
l
for
Z
n
|
Z
n
2
+
(
0.1
M
)
|
|
A
g
+
(
1.0
M
|
A
g
at
298
K
will be:
Q.
If
100
mL of
1.0
M
H
2
S
O
4
is mixed with
200
mL of
1.0
M
K
O
H
solution, molarity of the salt formed is
:
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