Electrophile: Electrophiles are reactants that are either positively charged or neutral.
Electrophile does not have a single pair of electrons which can be called electron-deficient species.
Positively charged or electron-deficient chemical species can accept electron pairs from other molecules or atoms and thus can accept an electron pair from electron-rich species.
Chlorine: Chlorine is a chemical element with the symbol Cl and atomic number 17.
Halogen is the second lightest element and appears between fluorine and bromine in the periodic table.
Chlorine is a yellowish-green gas at room temperature.
So, Cl is a Chlorine atom with 17 electrons which have 2,8,7 as electronic configuration.
Since, chlorine has 7 electrons, it has a vacancy for 1 electron, so it can act as an electrophile to complete its octet.
But on the other hand it has 3 lone pairs which can be donated to those who lack electrons..
The atomic form of chlorine has only three pairs of electrons, so it can donate by binding to other electron-deficient atoms or molecules.
In Cl- form chlorine acts as nucleophile and in Cl+ form as electrophile.