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Elementary and Complex Reactions

Is hydrolysis...

Question

Is hydrolysis of ester a type of neutralisation reaction??

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Solution

No. Ester + Water -------- Alcohol + Acid
The forward reaction is called ester hydrolysis and reverse reaction is called esterification reaction.

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Q. Acid hydrolysis of ester is first order reaction and rate constant is given by

k = \frac{2.303}{t} log \frac{V_{\infty} - V_{0}}{V_{\infty} - V_{t}}

V_{0}

V_{t}

V_{\infty}

are the volume of standard

N a O H

required to neutralise acid present at a given time, if ester is

50

% neutralised then :

Q. Acid hydrolysis of ester in first order reaction and rate constant is given by

k = \frac{2.303}{t} l o g \frac{V_{\infty} - V_{0}}{V_{\infty} - V_{t}}

V_{0}

V_{t}

V_{\infty}

are the volume of standard

N a O H

required to neutralise acid present at a given time, if ester is

50

neutralised then:

Q. Assertion :Fruit formation process shows increase in rate with passage of time. Reason: Hydrolysis of ester is a homogeneous autocatalytic reaction.

Q. In the hydrolysis of an ester in presence of large excess of water. the order of the reaction is

Q. Hydrolysis of ester give a carboxylic acid which on Kolbe's electrolysis yields ethane. The ester is:

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