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Chemical Properties of Aromatic Compounds

Is NH2 more e...

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Is NH2 more electron Donating than CH2^-(minus)??

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Q. Assertion :Coupling of

P h \oplus N H_{2}

with aniline is faster than with phenol. Reason: Aniline is more

- e

donating than phenol.

Q. Comment on the electron donating and withdrawing power of the following group.

- {N O}_{2}

- {N H}_{2}

Q. Assertion : Benzylamine is more basic than aniline.
Reason :

N H_{2}

group is electron releasing group.

Consider the following statements :

C H_{3} O \oplus C H_{2}

is more stable than

C H_{3} \oplus C H_{2}

{M e}_{2} \oplus C H

is more stable than

C H_{3} C H_{2} \oplus C H_{2}

C H_{2} = C H - \oplus C H_{2}

is more stable than

C H_{3} C H_{2} \oplus C H_{2}

C H_{2} = \oplus C H

is more stable than

C H_{3} \oplus C H_{2}

Out of these statements :

Q. What is the decreasing order of strength of the bases

O H^{-}, N H_{2}^{-}, H C \equiv C^{⊝}

C H_{3} - C H_{2}^{⊝}

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