Flux is a substance that is added during smelting to convert infusible impurities or gangue into fusible material known as slag.
SiO2 is a non-metallic or an acidic oxide. It can be used as an acidic flux to remove basic impurities such as CaO.
In the extraction of Fe, SiO2 is a gangue that is treated with basic flux (CaO) to form the fusible slag - calcium silicate.
CaO + SiO2 → CaSiO3
(Flux) (Impurities) (Slag)