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Question

Is sp3d2 hybridization the same as d2sp3 hybridization?

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Solution

sp3d2 hybridization is the mixing of s, p and d atomic orbitals of the same electron shell to form sp3d2 hybrid orbitals. There, one s atomic orbital, three p atomic orbitals and two d atomic orbitals mix with each other. This mixing results in six hybrid orbitals of same size and shape but different from their orientation.

d2sp3 hybridization is the mixing of s and p atomic orbitals of the same electron shell with d orbitals of another electron shell to form d2spp3 hybrid orbitals. This hybridization results in six hybrid orbitals.

Hence, sp3d2 and d2sp3 are not same.

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