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Question

is the most stable conformation of butane.

A
Gauche form
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B
Anti form
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C
Eclipsed form
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D
Fully eclipsed form
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Solution

The correct option is B Anti form

The lowest energy conformation will be the one, in which the two methyl groups are as far apart as possible i.e., 180 away form each other.

This conformation will be maximum staggered and is called anti conformation. Other conformations can be obtained by rotating one of the C2 or C3 carbon atoms through an angle of 60 as shown ahead.

The order of stability of these conformations is, Anti > Skew or Gauche > Eclipsed >Fully eclipsed.


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