Dear Student
Fuels are sources of "free energy", F The amount of F above the minimum in some environment is the amount of energy available to do large-scale work. A fuel like petrol can release lots of energy when it reacts with oxygen in the atmosphere. So petrol in an O2 atmosphere has lots of extra F. Water doesn't have any. The reason is very simple. Water is hydrogen that already has been burned. So it's not a fuel anymore.
Hope this helps you