Isothermally at 27∘C, one mole of a Van der Waal's gas expands reversibly from 2 liters to 20 liters. Calculate the work done if a = 1.42 × 1012 dynes cm4 per mole and b = 30 cc
Try to read the question properly.
Here the gas is vanderwaal's gas not ideal gas.
Do you recall the equation of vanderwaal's gas from last chapter
Let's try to recall it.
It was P = RTV − b − aV2
Now, we have
W = V2∫V1 PdV = V2∫V1 (RTV − b − aV2)dV
= [RTln(V − b) + aV]V2V1 = RTlnV2 − bV1 − b + a[1V2−1V1]
= 2.303 × 8.31 × 107 × 300 log20 − 0.032 − 0.03 + 1.42 × 1012[2 − 2020 × 2]
= −58124.67 × 107 ergs
= −58124.67 Joules