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Question

Isothermally at 27C, one mole of a Van der Waal's gas expands reversibly from 2 liters to 20 liters. Calculate the work done if a = 1.42 × 1012 dynes cm4 per mole and b = 30 cc


A
- 58.12 k J
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B
-861.2 k J
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C
-691.2 k J
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D
-761.2 k J
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Solution

The correct option is A - 58.12 k J

Try to read the question properly.

Here the gas is vanderwaal's gas not ideal gas.

Do you recall the equation of vanderwaal's gas from last chapter

Let's try to recall it.

It was P = RTV b aV2

Now, we have

W = V2V1 PdV = V2V1 (RTV b aV2)dV

= [RTln(V b) + aV]V2V1 = RTlnV2 bV1 b + a[1V21V1]

= 2.303 × 8.31 × 107 × 300 log20 0.032 0.03 + 1.42 × 1012[2 2020 × 2]

= 58124.67 × 107 ergs

= 58124.67 Joules


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