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Question

Isotopes of chlorine have the same number of electrons but differ in the number of neutrons. Why?

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Solution

Chlorine has two isotopes, 35Cl17 and 37Cl17.
Both isotopes have the same atomic number 17 and hence they have the same number of protons.
As the number of protons are same so the number of electrons will also be the same as these are electrically neutral species.
They differ only in their mass numbers and as mass number equals number of protons and neutrons, the isotopes differ in the number of neutrons.

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